Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/3464
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dc.contributor.authorSrikrishna, A-
dc.contributor.authorAnebouselvy, K-
dc.date.accessioned2009-03-25T04:01:30Z-
dc.date.available2009-03-25T04:01:30Z-
dc.date.issued2009-
dc.identifier.issn0376-4699-
dc.identifier.urihttp://hdl.handle.net/123456789/3464-
dc.description413-422en_US
dc.description.abstractFirst enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxythapsan-10-ol has been described. (R)-Carvone has been employed as the chiral starting material and a combination of intramolecular alkylation and Criegee fragmentation are employed for intramolecular stereospecific transfer of the chirality. An intramolecular diazoketone cyclopropanation and regioselective cyclopropane ring cleavage reactions have been employed for the creation of the three requisite contiguous quaternary carbon atoms.en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.sourceIJC-B Vol.48B(03) [March 2009]en_US
dc.subjectEnantiospecificen_US
dc.subjectThapsia garganicaen_US
dc.subjectthapsaneen_US
dc.subjectThapsia villosaen_US
dc.titleEnantiospecific total synthesis of ent-10,11-thapsan-10-olen_US
dc.typeArticleen_US
Appears in Collections:IJC-B Vol.48B(03) [March 2009]

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