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Title: Sodium paramolybdate revisited
Authors: Srinivasan, Bikshandarkoil R
Morajkar, Sudesh M
Keywords: Paramolybdate;Sodium;Hexasodium heptamolybdate 14-hydrate;Cyclic voltammetry
Issue Date: Jun-2016
Publisher: NISCAIR-CSIR, India
Abstract: The term paramolybdate refers to the species of formula [Mo7O24]6-. A convenient method for the rational synthesis of a sodium paramolybdate namely hexasodium heptamolybdate(VI) 14-hydrate Na6[Mo7O24]·14H2O and its spectral and thermal characterization are reported. Cyclic voltammetric and conductivity studies of an aqueous solution of Na6[Mo7O24]·14H2O reveal the presence of hydrated Na+ ions and heptamolybdate anions in solution unlike a sodium coordinated heptamolybdate in the solid state.
Page(s): 676-680
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.55A(06) [June 2016]

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