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Title: Tetraaquabis(4-methoxyphenylacetato-O') magnesium(II) dihydrate and catena-poly[[(diaqua)manganese(II)]- bis(μ2-4-methoxyphenylacetato-O,O')]: A monomeric and a two-dimensional coordination polymer based on 4-methoxyphenylacetic acid
Authors: Dhavskar, Kiran T
Srinivasan, Bikshandarkoil R
Keywords: Coordination polymer;Two-dimensional coordination polymers;Monodentate ligands;Bridging bidentate ligands;Methoxyphenylacetic acid;Manganese;Magnesium
Issue Date: 15-Feb-2016
Publisher: NISCAIR-CSIR, India
Abstract: The synthesis and characterization of tetraaquabis(4-methoxyphenylacetato-O')magnesium(II) dihydrate (1) and catena-poly[[(diaqua)manganese(II)]bis(μ2-4-methoxyphenylacetato-O,O')] (2) based on 4-methoxyphenylacetic acid (4-mpaH) ligand is reported. In 1, the unique 4-mpa functions as a monodentate ligand for Mg(II) situated on an inversion centre, resulting in a monomeric Mg(II) complex. The Mn(II) in 2 is also located on an inversion centre and the μ2-bridging bidentate coordination mode of the unique 4-mpa ligand results in the formation of a two-dimensional manganese coordination polymer.
Page(s): 170-176
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.55A(02) [February 2016]

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