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http://nopr.niscair.res.in/handle/123456789/33428| Title: | Piperazinediium bis(µ2-phthalato)zincate(II) monohydrate: A new ladder coordination polymer with a unique supramolecular architecture |
| Authors: | Jyai, Rita N Srinivasan, Bikshandarkoil R |
| Keywords: | Coordination chemistry;Coordination polymer;Ladder complexes;Supramolecular network;Bridging ligands;Phthalates;Metal phthalates;Zinc;Zinc phthalates;Piperazinediium bis(µ2-phthalato) zincate |
| Issue Date: | 23-Nov-2015 |
| Abstract: | The µ2-bridging bidentate coordination modes of the crystallographically unique phthalate ligands in piperazinediium bis(µ2-phthalato)zincate(II) monohydrate (1) result in Zn···Zn separations of 5.839(5) and 8.142(3) Å respectively leading to a one-dimensional Zn(II) ladder. The organic cation, ladder complex anion and lattice water in (pipH2)[Zn(pt)2]·H2O (1) (pipH2= piperazinediium, pt = phthalate) assemble into a unique supramolecular network, resulting in the following H-bonded sequence, viz., water···cation···water···ladder···water in the crystallographic ac plane. |
| Page(s): | 1402-1408 |
| URI: | http://hdl.handle.net/123456789/33428 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.54A(11) [November 2015] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 54A(11) 1402-1408_Suppl Data.pdf | Supplementary Data | 622.82 kB | Adobe PDF | View/Open |
| IJCA 54A(11) 1402-1408.pdf | Main Article | 250.27 kB | Adobe PDF | View/Open |
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