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Title: Dielectric studies on binary mixtures of methyl isobutyl ketone (MIBK) in non-polar solvents
Authors: Das, J K
Dash, S K
Chakravortty, V
Swain, B B
Issue Date: Jul-1994
Publisher: NISCAIR-CSIR, India
Abstract: Dielectric constants of binary mixtures of methyl isobutyl ketone (MIBK), an extractant used in nuclear industry, with non-polar solvents, viz., benzene, CCl4 and p-xylene have been measured at 303 K. The results are used to compute linear correlation factor, excess molar polarization and excess free energy of mixing in these mixtures using the Winkelmann-Quitzsch equation to interpret the liquid structure. The trend of variation of these factors indicates gradual conversion of ɑ-multimers to β-multimers on adding a non-polar diluent to MIBK.
Page(s): 230-232
ISSN: 0975-0991 (Online); 0971-457X (Print)
Appears in Collections:IJCT Vol.01(4) [July 1994]

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