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Title: Liquid-liquid extraction studies of some metal complexes using crown ethers
Authors: Gaikwad, A G
Noguchi, H
Yoshio, M
Issue Date: Sep-1995
Publisher: NISCAIR-CSIR, India
Abstract: liquid-liquid extraction investigations of Pd(II), V(V), Co(ID), Cu(II), Ni(II) and Fe(II)-PAR[4-(2pyridyl azo )-resorcinol complexes by using dicyclohexano-18-crown-6- have been carried out. Anioic complexes of Pd(II), V(V), Co(III), Cu(II), Ni(II) and Fe(III)-PAR extracted into organic phase as increase in order Pd > V> Co > Cu > Ni > Fe. During thermodynamic studies, it was observed that the entropy effect is one of the important factors responsible for the selective extraction. However, the shape of the complexes may be one of the causes for the selective change in entropy during the extraction of chelate. In effect, planar palladium-PAR-SCN-chelate was extracted selectively in comparison with other chelates.
Page(s): 271-275
ISSN: 0975-0991 (Online); 0971-457X (Print)
Appears in Collections:IJCT Vol.02(5) [September 1995]

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