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|Title:||Microwave assisted fast and clean conversion of mesylate to azide: Synthesis of (1S,2R/1R,2S)-1-azido-2-carbocyclic amines as immediate precursors to versatile 1,2-cis-diamines|
|Keywords:||Mesylate;Azide;Microwave irradiation;Diamines;Asymmetric catalysis;Medicinal agent|
|IPC Code:||Int.Cl.8 C07D|
|Abstract:||An efficient and rapid conversion of mesylate to azide under microwave irradiation has been carried out. It proceeds through inversion of configuration from chiral mesylates to provide optically pure cis-azides, immediate precursors of vicinal-cis-1,2-diamines. These diamines can serve as metal ligands in asymmetric catalysis and their derivatives can be employed as medicinal agents.|
|Appears in Collections:||IJC-B Vol.45B(06) [June 2006]|
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