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Title: Microwave assisted fast and clean conversion of mesylate to azide: Synthesis of (1S,2R/1R,2S)-1-azido-2-carbocyclic amines as immediate precursors to versatile 1,2-cis-diamines
Authors: Govindaraju, T
Keywords: Mesylate;Azide;Microwave irradiation;Diamines;Asymmetric catalysis;Medicinal agent
Issue Date: Jun-2006
Publisher: NISCAIR-CSIR, India
IPC Code: Int.Cl.8 C07D
Abstract: An efficient and rapid conversion of mesylate to azide under microwave irradiation has been carried out. It proceeds through inversion of configuration from chiral mesylates to provide optically pure cis-azides, immediate precursors of vicinal-cis-1,2-diamines. These diamines can serve as metal ligands in asymmetric catalysis and their derivatives can be employed as medicinal agents.
Page(s): 1492-1498
ISSN: 0042-6075
Appears in Collections:IJC-B Vol.45B(06) [June 2006]

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