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Title: Catalytic tri-reforming of glycerol for hydrogen generation
Authors: Kumar, M Ashwani
Venumadhav, Ch
Sagar, T V
Surendar, M
Lingaiah, N
Rao, G Nageswara
Prasad, P S Sai
Keywords: Catalysts;Supported catalysts;Nickel catalysts;Ceria;Zirconia;Glycerol;Tri-reforming;Synthesis gas;Hydrogen production
Issue Date: 19-Apr-2014
Abstract: Tri-reforming of glycerol has been carried out, for the first time, on CeO2, ZrO2 and CeO2-ZrO2 supported 10 wt.% Ni catalysts. The catalysts have been characterized by nitrogen adsorption, X-ray diffraction, temperature programmed reduction, scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy and tested for glycerol tri-reforming at atmospheric pressure and 673-1073 K. Ni/CeO2-ZrO2 has shown 95% of thermodynamic limit for hydrogen production, at 873 K. Also, the catalyst shows good stability.
Page(s): 530-534
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.53A(04-05) [April-May 2014]

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