Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/28461
Title: Methane reforming with carbon dioxide over La-Nix-Ce1-x mixed oxide catalysts
Authors: Sagar, T V
Sreelatha, N
Hanmant, G
Upendar, K
Lingaiah, N
Rao, Kamaraju Seetha Rama
Satyanarayana, C V V
Reddy, I A K
Prasad, P S Sai
Keywords: Catalysts;Carbon dioxide reforming;Dry reforming;Hydrothermal synthesis;Methane reforming;Mixed oxides;Nickel;Lanthanum;Cerium
Issue Date: Apr-2014
Publisher: NISCAIR-CSIR, India
Abstract: La-Nix-Ce1-x mixed oxide (0≤x≤1) catalysts have been hydrothermally prepared, characterized by physico-chemical techniques and evaluated for CO2 reforming of methane. High conversions are achieved for both methane and carbon dioxide over the LaNi0.6Ce0.4O3 catalyst tested under the conditions of CO2/CH4/N2 ratio of 80/80/80 (total flow rate = 240 mL/min), space velocity of 28,800 h-1 and at a temperature of 800 °C. The H2/CO ratio in the syngas is stable at 0.93±0.02. Exchanging Ni with Ce, rather than with La as reported in the literature, appears to be a better option for the improved performance of the catalysts.
Page(s): 478-483
URI: http://hdl.handle.net/123456789/28461
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.53A(04-05) [April-May 2014]

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