Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/2753
Title: Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group
Authors: Singh, Vishwakarma
Chandra, Girish
Mobin, Shaikh M
Keywords: Cycloaddition
Cyclohexa-2,4-dienone
Diels-Alder reaction
Bicyclo[2.2.2]octane
1,2-migration
Issue Date: Dec-2008
Publisher: CSIR
Abstract: Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienones with ethyl vinyl ether, butyl vinyl ether, vinyl acetate and vinyl phenyl sulphone leading to a stereoselective entry into bicyclo[2.2.2]octanes having quaternary methyl group is reported. A novel thermal 1,2-methyl migration has also been described.
Description: 1886-1891
URI: http://hdl.handle.net/123456789/2753
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.47B(12) December 2008]

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