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Title: Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group
Authors: Singh, Vishwakarma
Chandra, Girish
Mobin, Shaikh M
Keywords: Cycloaddition;Cyclohexa-2,4-dienone;Diels-Alder reaction;Bicyclo[2.2.2]octane;1,2-migration
Issue Date: Dec-2008
Publisher: CSIR
Abstract: Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienones with ethyl vinyl ether, butyl vinyl ether, vinyl acetate and vinyl phenyl sulphone leading to a stereoselective entry into bicyclo[2.2.2]octanes having quaternary methyl group is reported. A novel thermal 1,2-methyl migration has also been described.
Page(s): 1886-1891
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.47B(12) December 2008]

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