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NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.47B [2008] >
IJC-B Vol.47B(12) December 2008] >
| Title: | Synthesis of a stable, storable and differentially protected acyclic precursor of D-amicetose and its conversion to 4-O-benzyl-protected D-amicetose |
| Authors: | Aidhen, Indrapal Singh
Satyamurthi, N |
| Keywords: | Lactone
Homologation
Amide
Deoxysugar |
| Issue Date: | Dec-2008 |
| Publisher: | CSIR |
| Abstract: | Two carbon chain homolgation of enantiopure four carbon erythro configured iodo derivative 5 with N-methoxy-N-methyl-2-phenylsulfonylacetamide 6 affords for the first time a stable and storable precursor 3 of D-amicetose in the acyclic form, wherein the sensitive aldehyde is masked as a Weinreb amide. The differential protection in this acyclic derivative offers all the potential to exclusively arrive at the pyranose form of the target dideoxy-sugar. |
| Page(s): | 1851-1857 |
| ISSN: | 0376-4699 |
| Source: | IJC-B Vol.47B(12) December 2008]
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