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Title: Evaluation of excess Gibbs energy of mixing in the binary mixtures of tri-n-butyl phosphate in nonpolar solvents using dielectric probe
Authors: Ray, S K
Mohanty, B
Tripathy, S
Roy, G S
Issue Date: Feb-1999
Publisher: NISCAIR-CSIR, India
Abstract: Excess Gibbs energy of mixing has been evaluated in the binary mixtures of tri-n-butyl phosphate(TBP) in nonpolar solvents viz. benzene, carbon tetrachloride, p-xylene, n-heptane, cyclohexane and n-hexane. The (ΔGAB)maxima is in the order, benzene < carbontetrachloride < p-xylene < n-heptane < cyclohexane< n-hexane. TBP has maximum interaction in case of aromatic compound with benzene and least interaction with cyclohexane. In the case of aliphatic compounds the interaction is highest in the mixture of TBP + CCl4 and lowest in TBP +n-hexane.
Page(s): 127-132
ISSN: 0975-1041 (Online); 0019-5596 (Print)
Appears in Collections:IJPAP Vol.37(02) [February 1999]

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