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dc.contributor.authorSahoo, Prangya Rani-
dc.contributor.authorMishra, Bijay K-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstractPhenylthioureas have been subjected to oxidation in acetonitrile medium in neutral condition to investigate the oxidation behaviour of cetyltrimethylammonium permanganate on multifunctional groups. The oxidation product in each reaction is found to be the corresponding phenylurea. The rate of reaction is dependent on [CTAP], [phenylthiourea], [surfactant] and reaction temperature. A Michaelis-Menten type kinetics is observed with respect to the substrate. A reaction mechanism involving the formation of a cyclic intermediate in the slow step is proposed for the oxidation reaction. en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.53A(02) [February 2014]en_US
dc.subjectReaction mechanismen_US
dc.subjectCetyltrimethylammonium permanganateen_US
dc.titleOxidation of phenylthioureas by cetyltrimethylammonium permanganate: A kinetic studyen_US
Appears in Collections:IJC-A Vol.53A(02) [February 2014]

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