Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/26262
Title: Molal volume of multicomponent liquid mixtures of non electrolytes
Authors: Pandey, J D
Sharma, A K
Pandey, A.
Soni, N K
Mukherjee, Sushmita
Issue Date: Mar-2001
Publisher: NISCAIR-CSIR, India
Abstract: Inspite of tremendous impressive developments of the molecular theory, an engineer frequently finds the need for physical properties, which have not been measured. The molal volume of a fluid at a given pressure and temperature is an equilibrium thermodynamic property. In the present work, Wassiljewa equation in conjunction with Hildebrand's relation has been applied to evaluate molal volume of the various classes of liquid mixtures (binary, ternary and quaternary). It has the advantage over the empirical relations since it can be applied to a wide variety of fluids in moderate range. Moreover, it is very simple in form and the parameters have physical significance that is easy to conceive. It was observed after extensive fitting to the Hildebrand relation that V0 for most pure fluid range between 0.3 and 0.32 times the critical volume.
Page(s): 149-151
URI: http://hdl.handle.net/123456789/26262
ISSN: 0975-1041 (Online); 0019-5596 (Print)
Appears in Collections:IJPAP Vol.39(03) [March 2001]

Files in This Item:
File Description SizeFormat 
IJPAP 39(3) 149-151.pdf544.44 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.