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|Title:||[K(18C6)]2[Pt(SCN)4](H2O): A novel one-dimensional coordination polymer with K-N bonds|
|Abstract:||Pt (II) 18-crown-6 complex [K(18C6)]2[Pt(SCN)4](H2O) has been isolated and characterized by X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P21/ n with cell dimensions, a = 1.1116(1), b = 1.2258(1), c = 1.5856(1) nm, β = 93.479(9)o , V = 2.1567(3) nm3, Z = 2, R = 0.033 and Rw = 0.051 . In the solid state, the complex displays a one-dimensional infinite chain of two [K(18C6)]+ complex cations and a [Pt (SCN)4]2- anion bridged by one H2O molecule between adjacent [K(18C6)]+ units.|
|Appears in Collections:||IJC-A Vol.39A(09) [September 2000]|
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