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|Title:||Phenol-amide chelate of iron(III): Its redox activity with sulphur(IV)|
Dash, Anadi C
|Abstract:||The reaction of iron(III) complex of N,N-ethylene-bissalicylamide dianion (SALM), [Fe(SALM) (OH2)2]+, with SIV results in the formation of the monosulphito complex,[Fe(SALM)(OH2)(SO3)]- in two isomeric forms (cis and trans ) with pK =5.2 ± 0.1 (for the aqua ligand) and the aquasulphito/hydroxo -sulphito complexes undergo internal electron transfer, FeIII ← SIV,demonstrating the stereochemical control on the redox activity.|
|Appears in Collections:||IJC-A Vol.39A(09) [September 2000]|
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