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Title: Tandem Grignard addition/aromatic aza-Cope rearrangement route to the synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinoline derivatives
Authors: Huq, C A M A
Raj, A R Naresh
Keywords: Tandem reaction;1-N-vinyl-2-pyrrolidinone;Grignard addition;3,4-dihydropyrrolo [2,1-a] isoquinoline;Aromatic 3-aza-Cope rearrangement
Issue Date: Nov-2013
Publisher: NISCAIR-CSIR, India
Abstract: 3,4-Dihydropyrrolo[2,1-a]isoquinolines have been prepared by the tandem Grignard addition/aromatic aza-Cope rearrangement. The aza-Cope rearrangement involves the π bonds of the phenyl ring and vinylic moiety which forms the 1,5-hexadiene system necessary for a [3,3] sigmatropic rearrangement.
Page(s): 1451-1454
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.52B(11) [November 2013]

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