Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/22955
Title: Solvent extraction separation of bismuth(III) with hexaacetato calix(6)arene
Authors: Malkhede, D D
Dhadke, P M
Khopkar, S M
Issue Date: Jan-2000
Publisher: NISCAIR-CSIR, India
Abstract: Bismuth(III) was quantitatively extracted from 0.1 M HCl with 1×10-4M of hexaacetato calix(6)arene in toluene. It was stripped with 2 M nitric acid and determined from the aqueous phase spectrophotometrically at 470 nm as its complex with thiourea. The various parameters such as pH, reagent concentration, kind of diluents, stripping agents, effect of diverse ions were studied to ascertain optimum conditions for the quantitative extraction of bismuth . Bismuth was separated from thorium(IV), iron(III), manganese(II), chromium(III). lead(II), palladium(II) and thallium(III) in multicomponent mixtures. The method was extended for the analysis of bismuth in real samples.
Page(s): 7-10
URI: http://hdl.handle.net/123456789/22955
ISSN: 0975-0991 (Online); 0971-457X (Print)
Appears in Collections:IJCT Vol.07(1) [January 2000]

Files in This Item:
File Description SizeFormat 
IJCT 7(1) 7-10.pdf696.18 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.