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Title: Diels-Alder approach for the synthesis of spiro compounds related to Fredericamycin A
Authors: Sudini, Ravinder R
Khire, Uday R
Pandey, Rajesh K
Kumar, Pradeep
Issue Date: Oct-2000
Publisher: NISCAIR-CSIR, India
Abstract: The synthesis of a variety of spirodiones 7,12 related to fredericamycin A 1 has been reported. The preparation of DielsA-lder adducts employing the nonfunctionalised and functionalised isobenzofurans 13, 14 as dienes and spirodiones 7, 12 as dienophiles has been described. The subsequent acid induced rearrangement of Diels-Alder adducts 15, 17, 19, 21 leads to the formation of spiro compounds 16, 18, 20, 22 related to fredericamycin A.
Page(s): 738-745
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.39B(10) [October 2000]

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