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IJC-A Vol.46A(12) [December 2007] >


Title: Synthesis and crystal structure of an iron(II) dimeric complex
Authors: Roy, Partha
Dhara, Koushik
Chakraborty, Jishnunil
Nethaji, Munirathinam
Banerjee, Pradyot
Issue Date: Dec-2007
Publisher: CSIR
IPC CodeInt Cl.⁸ C07F15/02
Abstract: An iron(II) complex, [Fe₂(salen)₂] has been prepared by the reaction of [Feˡˡˡ(salen)Cl] with copper(II) malonate dihydrate [salen = N,N′-ethylenebis(salicylideneiminato) dianion] in N,N-dimethylformamide-water mixture. The complex has been characterized by FT-IR spectroscopy, UV-vis spectra, thermogravimetric analysis, cyclic voltammetry and X-ray crystallography. The iron(II) complex 1 crystallizes in the monoclinic, space group C2/c, a = 26.664(5) Å, b = 6.9943(11) Å, c = 14.727(2) Å, β = 97.498(3)º, and Z = 8. The structural study reveals that it is a penta-coordinate Fe(II) dimeric complex.
Page(s): 1947-1950
ISSN: 0376-4710
Source:IJC-A Vol.46A(12) [December 2007]

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