|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(12) [December 2007] >
| Title: | Synthesis and crystal structure of an iron(II) dimeric complex |
| Authors: | Roy, Partha
Dhara, Koushik
Chakraborty, Jishnunil
Nethaji, Munirathinam
Banerjee, Pradyot |
| Issue Date: | Dec-2007 |
| Publisher: | CSIR |
| IPC Code: | Int Cl.⁸ C07F15/02 |
| Abstract: | An iron(II) complex, [Fe₂(salen)₂] has been prepared by the reaction of [Feˡˡˡ(salen)Cl] with copper(II) malonate dihydrate [salen = N,N′-ethylenebis(salicylideneiminato) dianion] in
N,N-dimethylformamide-water mixture. The complex has been characterized by FT-IR spectroscopy, UV-vis spectra, thermogravimetric analysis, cyclic voltammetry and X-ray crystallography. The iron(II) complex 1 crystallizes in the monoclinic, space group C2/c, a = 26.664(5) Å, b = 6.9943(11) Å, c = 14.727(2) Å, β = 97.498(3)º, and Z = 8. The structural study reveals that it is a penta-coordinate Fe(II) dimeric complex. |
| Page(s): | 1947-1950 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(12) [December 2007]
|
|
