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|Title:||Synthesis and crystal structure of an iron(II) dimeric complex|
|IPC Code:||Int Cl.⁸ C07F15/02|
|Abstract:||An iron(II) complex, [Fe₂(salen)₂] has been prepared by the reaction of [Feˡˡˡ(salen)Cl] with copper(II) malonate dihydrate [salen = N,N′-ethylenebis(salicylideneiminato) dianion] in N,N-dimethylformamide-water mixture. The complex has been characterized by FT-IR spectroscopy, UV-vis spectra, thermogravimetric analysis, cyclic voltammetry and X-ray crystallography. The iron(II) complex 1 crystallizes in the monoclinic, space group C2/c, a = 26.664(5) Å, b = 6.9943(11) Å, c = 14.727(2) Å, β = 97.498(3)º, and Z = 8. The structural study reveals that it is a penta-coordinate Fe(II) dimeric complex.|
|Appears in Collections:||IJC-A Vol.46A(12) [December 2007]|
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