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Title: Synthesis, spectroscopic and structural studies on N-(2–hydroxyphenyl)cinnamaldimine and some bivalent metal complexes
Authors: De, Rajib Lal
Mandal, Mahuya
Roy, Lovely
Mukherjee, Jaydeep
Bhawal, Ruchika
Maiti, Kamales
Issue Date: Oct-2008
Publisher: CSIR
IPC Code: Int. Cl. ⁸ CO7C251/02; CO7F1/08; CO7F3/06; CO7F15/04; CO7F15/06
Abstract: The bidentate Schiff base, CINOPH, obtained from the condensation of cinnamaldehyde with 2-aminophenol undergoes facile complexation reactions to form Mˡˡ(CINOP)₂(M= Cu, Ni, Co and Zn). In these complexes coordination is through imino nitrogen (-CH=N-) and amino phenolic (-OH) oxygen as revealed by the results of their elemental analyses, spectral, magnetic and electrochemical properties and single crystal X-ray crystallographic structure analysis performed on CINOPH (monoclinic, C2/c; Z, 8) and Cu(CINOP)₂( monoclinic, C2/c; Z, 4).
Page(s): 1480-1485
ISSN: 0376-4710
Appears in Collections: IJC-A Vol.47A(10) [October 2008]

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