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Title: Kinetics and mechanism of oxidation of 4-oxoacids by hexacyanoferrate(III) catalysed by Os(VIII)
Authors: Rani, D Freeda Gnana
Pushparaj, FJ Maria
Alphonse, I
Rangappa, K S
Issue Date: Oct-2002
Publisher: NISCAIR-CSIR, India
Abstract: Kinetics of Os(VIII) catalysed oxidation of substituted and unsubstituted 4-oxoacids by alkaline hexacyanoferrate(III) in sodium carbonate-bicarbonate buffer have been studied. The reaction is zero order in oxidant, first order with respect to Os(VIII), first order at higher concentrations and zero order at lower concentrations with respect to both substrate and alkali. The activation parameters have been computed.
Page(s): 2153-2159
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.41B(10) [October 2002]

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