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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(11) [November 2007] >
| Title: | Synthesis, crystal structure and biological activity of a new complex,+ bis(1,1-diethyl-3-(3-fluorobenzoyl)-thiourea)nickel(II) |
| Authors: | Zhang, You-Ming
Pang, Hai-Xia
Cao, Cheng
Wei, Tai-Bao |
| Issue Date: | Nov-2007 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl. ⁸ CO7F15/04 |
| Abstract: | A new complex bis(1,1-diethyl-3-(3-fluorobenzoyl)-thiourea) nickel (II) (NiL₂) has been synthesized and characterized by IR, ¹H NMR, ¹³C NMR spectra and elemental analysis. Structure of the complex has been determined by single crystal X-ray diffraction (CCDC 633339). The two ligand molecules adopt a cis-conformation bonded to the Ni(II) ion and the central nickel ion has four-coordination square-planar geometry contributed by two S and two carbonyl O atoms. Both the complex NiL₂ and its free ligand HL (1,1-diethyl-3-(3-fluorobenzoyl)-thiourea) exhibit powerful plant growth regulating activity towards the root of rape and compared with the free ligand HL. The complex NiL₂ displays more promoting activity in lower concentrations. |
| Page(s): | 1787-1791 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(11) [November 2007]
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