Please use this identifier to cite or link to this item:
|Title:||Synthesis and characterization of dinuclear molybdenum(VI) peroxo complexes with aroyl hydrazones|
Sheikh, H N
Kalsotra, B L
|Series/Report no.:||Int. Cl. ⁸ C07F11/00|
|Abstract:||The reactions of ammonium molybdate with hydrogen peroxide and ethanolic solutions of aroylhydrazones, viz. benzoic acid [1-(Furan-2-yl) methylene] hydrazide (BFMH), benzoic acid [(thiophen-2-yl)methylene] hydrazide (BTMH), benzoic acid [1-(thiophen-2-yl) ethylidene] hydrazide (BTEH), benzoic acid (phenyl methylene) hydrazide (BPMH) and benzoic acid [1-(anisol-3-yl) methylene] hydrazide (BAMH), result in the precipitation of the dinuclear complexes, Mo₂O₄(O₂)₂L-L(H₂O)₄ (where L-L = BFMH, BTMH, BTEH, BPMH and BAMH). The complexes have been characterized by elemental analysis, and studies on conductivity and magnetic susceptibility, IR and electronic spectra, ¹H NMR spectra, and TGA/DTA. The dinuclear complexes have been found to preserve the individuality of the molybdenum oxo peroxo core. The complexes exhibit significant in vitro antifungal effects against the Keretolytic fungus as compared to ligands.|
|Appears in Collections:||IJC-A Vol.46A(09) [September 2007]|
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.