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Title: Benzimidazolium dichromates : Efficient reagents for selective oxidation of alcohols to carbonyl compounds
Authors: Ramaiah, K
Dubey, P K
Ramanatham, J
Kumar, C Ravi
Grossert, J S
Issue Date: Jul-2003
Publisher: NISCAIR-CSIR, India
Abstract: Benzimidazolium dichromates have been used for the selective and efficient oxidation of simple alcohols to carbonyl compounds. 2-Methylbenzimidazolium dichromate has been used as a standard compound. It has been found to oxidize selectively, primary alcohols to aldehydes, without any over-oxidation, and secondary alcohols to ketones. Of the several solvents explored, acetic acid at RT has been found to be the best medium for oxidation.
Page(s): 1765-1767
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.42B(07) [July 2003]

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