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Title: A convenient enantiospecific methodology for (-)-(1R,5S)-1 ,5-dimethylbicyclo[3.3.0]octa-2,7-dione: A formal total synthesis of (-)-ceratopicanol
Authors: Srikrishna, A
Babu, N Chandrasekhar
Dethe, Dattatraya H
Issue Date: Jul-2003
Publisher: NISCAIR-CSIR, India
Abstract: An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundantly available monoterpene (R)-limonene is described. A combination of Claisen rearrangement- intramolecular diazo ketone cyclopropanation-regiospecific reductive cyclopropane cleavage reactions are employed for the stereo- and regiospecific generation of the two vicinal ring junction quaternary carbon atoms.
Page(s): 1688-1690
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.42B(07) [July 2003]

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