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IJC-A Vol.46A [2007] >
IJC-A Vol.46A(08) [August 2007] >
| Title: | Preparation, crystal structure and thermal decomposition of phenylenediammonium dichloride salts |
| Authors: | Kapoor, Inder Pal Singh
Srivastava, Pratibha
Singh, Gurdip |
| Issue Date: | Aug-2007 |
| Publisher: | CSIR |
| Abstract: | Phenylene-1,2-diammonium dichloride (P-1,2-DADCl), phe¬nylene-1,3-diammonium dichloride (P-1,3-DADCl), phenylene-1,4-diammonium dichloride (P-1,4-DADCl) and 5-carboxyl-phe¬nylene-1,3-diammonium dichloride (5-carboxyl-P-1,3-DADCl) salts have been prepared and characterized by elemental, spectral, gravimetric and X-ray crystallography. Thermal decomposition of these salts has been studied by TG and DSC and shows involvement of proton transfer as a primary step. Kinetic analysis of TG data has been evaluated by model fitting method and model free isoconversional methods. |
| Page(s): | 1277-1282 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(08) [August 2007]
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