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Title: Peroxidative oxidation of cycloalkane by di-, tetra- and polynuclear copper(II) complexes
Authors: Nandi, Mahasweta
Roy, Partha
Keywords: Oxidation;Peroxidative oxidation;Reaction mechanism;Polynuclear complexes;Copper
Issue Date: Oct-2013
Publisher: NISCAIR-CSIR, India
Abstract: Di-, tetra- and polynuclear copper(II) complexes with N2O donor system, [Cu2(L1)(μ2-pz)(CH3COO)2] (1), [Cu4(L1)24-O)(μ2-CH3COO)21,1-N3)(N3)] (2) and [Cu2(L2)(μ1,1-N3)(μ1,3-N3)2] (3) respectively (where pz = pyrazolato, HL1 = 2,6-bis(morpholinomethyl)-4-tert-butylphenol and HL2 = 2,6-bis(morpholinomethyl)-4-methylphenol) have been employed as catalysts for the peroxidative oxidation of cyclohexane and cycloheptane in the presence of hydrogen peroxide as the oxidant at room temperature and under atmospheric pressure. The oxidized products of cyclohexane are cyclohexanol and cyclohexanone, whereas cycloheptane is oxidized to cycloheptanol and cycloheptanone.
Page(s): 1263-1268
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.52A(10) [October 2013]

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