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Title: Unusual migrations and cyclization in the preparation of β-azido alcohols from β-hydroxy esters
Authors: Madhusudhan, G
Reddy, G Om
Ramanatham, J
Dubey, P K
Issue Date: Dec-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int.Cl.7 C 07 D317/00
Abstract: Migration of TBDMS and Boc groups from 2o alcohols to 1o alcohols during the reduction of β-hydroxy esters has been observed.Also, unusual cyclization has been noticed during tosylation of benzylic alcohol in tert-butyl ((2R)-2-hydroxy-2- phenyl ethyl)carbonate with SN2 in version.
Page(s): 2719-2723
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.43B(12) December 2004]

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