NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.47A [2008] >
IJC-A Vol.47A(08) [August 2008] >

Title: Kinetics and mechanism of Mn(II) catalyzed oxidation of acridine yellow by chloramine-T
Authors: Pare, Brijesh
Ayachit, Manisha
Jonnalagadda, S B
Issue Date: Aug-2008
Publisher: CSIR
IPC CodeInt. Cl.⁸ C07B33/00; C09B15/00
Abstract: The kinetics and mechanism of the uncatalyzed and Mn(II) catalyzed oxidation of acridine yellow(3,6-diamino-2,7-dimethyl acridine hydrochloride) dye by chloramine-T in acidic media has been studied using spectrophotometry. With excess concentrations of other reactants, the reaction rate follows pseudo first order kinetics with respect to acridine yellow. The uncatalyzed reaction has fractional order dependence on chloramine-T as well as on H+ concentration. The catalyzed reaction follows first order kinetics in catalyst [Mn(II)]. Variations of ionic strength has no influence on the reaction rate suggesting that neutral charged species are involved in the rate determining step. Increase in the addition of p-toluenesulfonamide results in decrease in rate constant values. The basic stoichiometric equation is as follows: AY⁺ + ArSO₂NHCl + H₂O = P⁺ + ArSO₂NH₂ +CH₃CH₂OH + CH₃CN + 2HCl, where P⁺ = 7-aminoquinoline-2, 3-dicarboxylic acid. The lowest catalytic limit for Mn(II) has been found to be 1.0x10⁻⁸ mol dm⁻³. On the basis of various kinetic investigations and product analysis mechanisms have been proposed.
Page(s): 1222-1225
ISSN: 0376-4710
Source:IJC-A Vol.47A(08) [August 2008]

Files in This Item:

File Description SizeFormat
IJCA 47A(8) 1222-1225.pdf98.56 kBAdobe PDFView/Open
 Current Page Visits: 1088 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 163267 since 01-Sep-2015  Last updated on 21-Jun-2016Webmaster: