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Title: Oxidation of diols by cetyltrimethylammonium dichromate
Authors: Patel, Sabita
Sung, Dae Dong
Mishra, B K
Issue Date: Aug-2008
Publisher: CSIR
Series/Report no.: Int. Cl.⁸ C07B33/00
Abstract: The oxidation kinetics of some diols have been investigated using cetyltrimethylammonium dichromate as the oxidant in dichloromethane in the presence of acetic acid and a cationic surfactant. A tentative mechanism has been proposed on the basis of (i) observed rate constant dependencies on the reactants, (ii) high negative entropy change and (iii) the kobs dependencies on surfactant concentration.
Description: 1218-1221
ISSN: 0376-4710
Appears in Collections:IJC-A Vol.47A(08) [August 2008]

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