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Title: Synthesis and physicochemical characterization of some Schiff base complexes of chromium(III)
Authors: Dubey, R K
Dubey, U K
Mishra, C M
Issue Date: Aug-2008
Publisher: CSIR
Abstract: Some chromium(III) complexes of the type, [Cr(L)₂ (H₂O)₂]Cl (1-10) [where L = Schiff bases (sbH, derived from the condensation of 2-amino pyridine, 2-aminophenol, o-toluidine, p-toluidine, 3-nitroaniline and anthranilic acid with salicylaldehyde/vanillin) and substituted benzimidazole/ benzoxazole or mercaptobenzimidazole] have been prepared by the reaction of chromium(III) chloride with corresponding ligands followed by immediate addition of ethanolic solution of anhydrous sodium acetate in 1:2 molar ratio. The resulting products have been characterized by elemental analysis, spectral (IR, UV-visible and FAB-mass) as well as magnetic susceptibility measurements. Octahedral structure is proposed for the complexes.
Page(s): 1208-1212
ISSN: 0376-4710
Source:IJC-A Vol.47A(08) [August 2008]

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