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Title: First report of structurally characterized dimorph of an oxovanadium(V)-hydrazonato complex containing V₂O₃⁴⁺ core
Authors: Mondal, Bipul
Drew, Michael G B
Ghosh, Tapas
Issue Date: Aug-2008
Publisher: CSIR
IPC Code: Int. Cl.⁸ C07F9/00
Abstract: The orthorhombic crystalline variety (with Pbca space group) of the title complex [V₂O₃(L)₂], incorporating the doubly deprotonated tridentate benzoyl hydrazone of 2-hydroxy-5-methylacetophenone has been synthesized from the decomposition of [VIVO(L)(bipy)] complex in CH₂Cl₂ and structurally characterized in contrast to its recently reported monoclinic variety (with C2/c space group) obtained from the reaction of [VO(acac)₂] with H₂L in acetone.
Page(s): 1204-1207
ISSN: 0376-4710
Appears in Collections:IJC-A Vol.47A(08) [August 2008]

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