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IJC-A Vol.47A [2008] >
IJC-A Vol.47A(08) [August 2008] >


Title: Synthesis, characterization and catalytic properties of microporous silicotitaniumphosphate by neutral templating route
Authors: Sarkar, Krishanu
Nandi, Mahasweta
Bhaumik, Asim
Issue Date: Aug-2008
Publisher: CSIR
IPC CodeInt. Cl. ⁸ B01J21/00; B01J29/00; B01J37/00
Abstract: A new series of microporous silicotitaniumphosphate and its organic-inorganic hybrid analogue have been synthesized under hydrothermal condition with the assistance of a neutral structure-directing agent, 4,4'-trimethylenedipiperidine under almost neutral pH condition. PXRD, FE-SEM, TEM and N₂ sorption studies have been used to characterize these materials. FTIR and UV-visible studies suggest the presence of Si-O-P and Ti-O-Si bonds, and tetrahedral coordination of Ti(IV) in the samples. The thermal stability of the materials has been analyzed by TGA/DTA. These samples show good catalytic activity towards the liquid phase partial epoxidation of cyclohexene and styrene using dilute H₂O₂ as oxidant.
Page(s): 1181-1186
ISSN: 0376-4710
Source:IJC-A Vol.47A(08) [August 2008]

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