NISCAIR Online Periodicals Repository

NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR)  >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.47A [2008] >
IJC-A Vol.47A(07) [July 2008] >


Title: Double aromatic amine addition across ruthenium(III) coordinated bis-nitrile function
Authors: Chatterjee, Sudipta
Nethaji, M
Goswami, Sreebrata
Issue Date: Jul-2008
Publisher: CSIR
IPC CodeInt. Cl. ⁸ C07F15/00
Abstract: Double aromatic amine addition reaction at a bisacetonitrile complex of ruthenium(III) is reported here. The cationic complex, cis-[(acac)₂Ru(CH₃CN)₂](ClO4) (1) [acac = acetylacetonate] reacts with aniline in neat to produce an orange bis-amidine complex, [RuIII(acac)₂{HN=C(Me)NHPh}₂](ClO₄), [2]ClO₄ in 60% yield. X-ray structure of the complex is also reported. The reaction occurs with addition of two equivalents of PhNH₂ across the two coordinated acetonitrile ligands. Optical spectra and redox properties of the complex have been discussed. It shows a reversible Ru(III)/Ru(II) response at -0.6 V and its visible spectrum is dominated by a broad ligand to metal charge transfer at 505 nm.
Page(s): 992-995
ISSN: 0376-4710
Source:IJC-A Vol.47A(07) [July 2008]

Files in This Item:

File Description SizeFormat
IJCA 47A(7) 992-995.pdf335.52 kBAdobe PDFView/Open
 Current Page Visits: 490 
Recommend this item

 

National Knowledge Resources Consortium |  NISCAIR Website |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2012 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 510022 since 06-Feb-2009  Last updated on 11-Apr-2014Webmaster: nopr@niscair.res.in