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Title: A simple method to predict the solvation free energy and enthalpy of electrolytes in aqueous and non-aqueous solutions
Authors: Badarayani, Rohini
Kumar, Anil
Issue Date: Jun-2000
Publisher: NISCAIR-CSIR, India
Abstract: A simple method is proposed to predict the solvation free energy of electrolytes in the aqueous and non-aqueous solutions upto 623 K. The solvation free energies are calculated by a suitable combination of scaled particle theory and modified Born equation. The method is applied to a variety of solutions and at various temperatures. The temperature derivative of solvation free energy with respect to temperature offers reasonably accurate estimations of entropy and enthalpy of solvation.
Page(s): 584-588
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.39A(06) [June 2000]

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