NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.47A [2008] >
IJC-A Vol.47A(06) [June 2008] >

Title: Synthesis of organoheterobimetallic [Bu₂Sn(IV)-Ti(IV)]-μ-oxoisopropoxide and its β-diketonates
Authors: Sharma, H K
Kumar, Rajesh
Issue Date: Jun-2008
Publisher: CSIR
Abstract: A new organoheterobimetallic-μ-oxoisopropoxide of the type [Bu₂SnO₂Ti₂(OPri)₆] has been synthesized by the thermal condensation of dibutyltin diacetate and titanium isopropoxide in 1:2 molar ratio in refluxing xylene. The isopropoxy substitution reactions of this μ-oxoisopropoxide compound with β-diketones in different molar ratios (1:1-1:4) gives compounds of the type [Bu₂SnO₂Ti₂(OPri)₆₋ոLո] (where n is 1-4 and L = acetylacetonate/ benzoylacetonate anion) respectively. The μ-oxoisopropoxide compound has been characterized by elemental, spectral analysis (IR, ¹H , ¹³C, ¹¹⁹Sn NMR and mass) and molecular weight data. The β-diketonates of [Bu₂SnO₂Ti₂(OPri)₆] have been characterized by elemental, liberated isopropanol and spectral analysis (IR, ¹H , ¹³C NMR).
Page(s): 854-858
ISSN: 0376-4710
Source:IJC-A Vol.47A(06) [June 2008]

Files in This Item:

File Description SizeFormat
IJCA 47A(6) 854-858.pdf258.41 kBAdobe PDFView/Open
 Current Page Visits: 743 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 170027 since 01-Sep-2015  Last updated on 30-Jun-2016Webmaster: