Please use this identifier to cite or link to this item:
http://nopr.niscair.res.in/handle/123456789/21085Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Naskar, Jnan Prakash | - |
| dc.contributor.author | Datta, Dipankar | - |
| dc.date.accessioned | 2013-09-13T08:51:09Z | - |
| dc.date.available | 2013-09-13T08:51:09Z | - |
| dc.date.issued | 2000-04 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/21085 | - |
| dc.description | 378-380 | en_US |
| dc.description.abstract | Electrochemistry of Cu(nqo)2 and Cu(nqo)2.im (nqo = 1-nitroso-2-naphtholate anion, im ≡ imidazole) has been studied in acetonitrile by cyclic voltammetry and coulometry at platinum electrodes under N2 atmosphere. The square planar complex Cu(nqo)2 shows a quasireversible Cu(I/II) couple at -0.30 V and a quasireversible Cu(II/III) couple at 0.78 V vs saturated calomel electrode. This is the first report of the observation of a Cu(II/III) couple in a CuN2O2 chromophore. The potentials of both the couples are lowered in the pentacoordinated species Cu(nqo)2.im. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.39A(04) [April 2000] | en_US |
| dc.title | Electrochemical studies on CuN2O2 chromophore | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.39A(04) [April 2000] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(4) 378-380.pdf | 592.32 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.