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Title: Nitrite linkage isomerization promoted by alkyne insertion in ruthenium organometallics
Authors: Chattopadhyay, Swarup
Ghosh, Kaushik
Pattanayak, Sujay
Chakravorty, Animesh
Issue Date: Jan-2001
Publisher: NISCAIR-CSIR, India
Abstract: The title transformation is of type η2-nitrite → η1 nitrite and it occurs upon reacting carbonyl(η2-nitrito)[4-methyl-6-(N-p-tolyl-imino)phenol] bis (triphenylphosphine) ruthenium(II) with acetylene in warm CH2Cl2-MeOH medium affording carbonyl (η1-nitrito) [2- vinyl -4- methyl -6-(N-p-tolyl-imino) phenolato] bis(triphenylphosphine) ruthenium(II) in which the iminium function is involved in weak bifurcated hydrogen bonding with phenolato oxygen and a nitrite oxygen atom.
Page(s): 1-3
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.40A(01) [January 2001]

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