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IJC-A Vol.47A(04) [April 2008] >

Title: Thermodynamics and kinetic studies of insertion reaction between CCl and NH₃
Authors: Si, Weijiang
Zhuo, Shuping
Issue Date: Apr-2008
Publisher: CSIR
Abstract: Based on the quantum theoretical study of the insertion reaction of CCl with NH₃, the statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the thermodynamic functions, the equilibrium constants, A factors and the rate constants in the temperature range 200-2000K. Results show that the reaction is thermodynamically dominant at low temperatures and kinetically favoured at higher temperatures.
Page(s): 556-559
ISSN: 0376-4710
Source:IJC-A Vol.47A(04) [April 2008]

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