Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/20834
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dc.contributor.authorMandal, A-
dc.contributor.authorKoll, A-
dc.contributor.authorFilarowski, A-
dc.contributor.authorMukherjee, S-
dc.date.accessioned2013-08-27T04:46:23Z-
dc.date.available2013-08-27T04:46:23Z-
dc.date.issued2002-06-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/20834-
dc.description1107-1111en_US
dc.description.abstractOne new ortho-hydroxy Schiff base, 2-(N-benzyl-α-iminoethyl)-naphthol (BEIN) in which the hydrogen atom in the CC(H)=N group is replaced by a methyl substituent, is synthesized. The crystal structure is determined and ab initio calculations with B3LYP/6-31G** basis sets are performed. The O ... N distance found in the O-H ... N hydrogen bond turns out to be quite short and is equal to 2.499 Å. This shortening is due to the steric repulsion of methyl substituent group and results in strengthening of the hydrogen bond.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.41A(06) [June 2002]en_US
dc.titleStrengthening of the intramolecular O... H... N hydrogen bond in 2-(N-benzyl-α-iminoethyl)-naphthol as a result of steric repulsionen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.41A(06) [June 2002]

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