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Title: Synthesis, characterization and thermal studies of some new organotin (IV) complexes with aniline N-thiohydrazide and benzaldehyde aniline N-thiohydrazone
Authors: Kaushik, N K
Mishra, A K
Issue Date: Nov-2003
Publisher: NISCAIR-CSIR, India
Abstract: The complexes of parac hlorotribenzyltin (IV) chloride and parachlorodibenzyl tin (IV) di chloride with an iline Nlhiohydrazide (L1), and benza ldehyde aniline N-thiohydrazone (L2) have been synthesized. The complexes have been characterized by elemental analysis and spectral (UV-VIS, IR & NMR) studies. Ligand in the complexes acts as bidentate and coordination takes place through sulphur and terminal nitrogen. These are 1:1 metal ligand complexes. Various thermodynamic parameters have been calculated for the decompos iti on steps using TG-DTA curves. Activity of all the complexes Vs. Rhizoctonia bataticola fungal strain have been studied and the general order of activity have been deduced.
Page(s): 2762-2766
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.42A(11) [November 2003]

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