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Title: Viscosity of 1-propanol + ethylene glycol dimethyl, + diethylene glycol dimethyl, + triethylene glycol dimethyl, and + tetraethylene glycol dimethyl ethers at 288.15, 298.15 and 308.15 K
Authors: Pal, Amalendu
Kumar, Anil
Issue Date: Nov-2003
Publisher: NISCAIR-CSIR, India
Abstract: The viscosity (η) in binary liquid mixtures of 1-propanol with ethylene glycol dimethyl ether (1,2-dimethoxyethane), CH3OCH2CH2OCH3, diethylene glycol dimethyl ether [bis(2-methoxyethyl)ether] , CH3OCH2CH2OCH2CH2OCH3, triethylene glycol dimethyl ether [1,2-bis(2-methoxyethoxy)ethane] , CH3OCH2(CH2OCH2)2CH2OCH3, and tetraethylene glycol dimethyl ether (2,5,8, 11,14-pentaoxapentadecane), CH3OCH2(CH2OCH2),CH2OCH3, have been measured as a function of mole fraction at 288.15, 298.15, and 308.15 K. The values of the quantity Δη, which refer to the deviations of the experimental values of the dynamic viscosities of the mixtures from the mo le fraction mixture law values, have been found to be negative for all the mixtures. Further, the excess free energies of activation of viscous flow (ΔG*E), have been calculated from the experimental data. The results for η, Δη and ΔG*E are discussed in terms of interactions between the components of the mixtures. Furthermore, activation enthalpies ΔH*E), and enthalpies of viscous flow (ΔS*E) have been evaluated and their variation with concentration is discussed.
Page(s): 2708-2716
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.42A(11) [November 2003]

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