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dc.contributor.authorChaudhury, Pradeep K-
dc.contributor.authorNagarajan, Kowliki-
dc.contributor.authorKumar, Anil-
dc.contributor.authorMaiti, Rabindranath-
dc.contributor.authorDas, Samar K-
dc.contributor.authorSarkar, Sabyasachi-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstract[Bu4N]2[MoVIO2(mnt)2] readily reacts with thiophenol leading to its reduction to [Bu4N]2[MoVIO2(mnt)2]. Detailed kinetics of this reaction is presented. The kinetics consists of three consecutive irreversible first order reactions (in the presence of excess of thiophenol) with k1, k2, k3 = 2.82(6) × 10-1 s-1 , 6.09(5) × 10-2 s-1 ,1.66(8) × 10-3 s-1 and 2.91(4) × 10-1 s-1, 6.15(3) × 10-2 s-1, 3.41(6) × 10-3 s-1 at 298 K in acetonitrile and aqueous-acetonitrile media respectively.en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.42A(09) [September 2003]en_US
dc.titleRedox reaction between [Bu4N]2[MoVIO2(mnt)2] and thiophenol in relevance to the autoreduction in the crystallization process of oxidized form of sulfite oxidaseen_US
Appears in Collections:IJC-A Vol.42A(09) [September 2003]

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