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Title: Ligand exchange reactions of sodium nitroprusside in the presence of sulphate ion under photochemical conditions
Authors: Mehta, Mayank R
Vyas, Piyush J
Vardia, Jitendra
Ameta, Suresh C
Issue Date: Jul-2003
Publisher: NISCAIR-CSIR, India
Abstract: Sodium nitroprusside contains cyanide ligands that are not easily replaced chemically. An effort has been made to substitute this ligand by another anionic ligand like sulphate. The rate of this photochemical reaction has been observed spectrophotometrically. The effects of different parameters like pH, light intensity, concentration of sodium nitroprusside and sulphate ligand concentration on the rate of this substitution reaction have been studied. The product is isolated and characterized. A tentative mechanism for this photochemical substitution reaction has been proposed.
Page(s): 1671-1673
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.42A(07) [July 2003]

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