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|Title:||Kinetics and mechanism of oxidation of hippuric acid with Bi(V) in phosphoric acid medium|
|Authors:||Mishra, P M|
Jha, A K
Jha, C S
|Abstract:||Kinetics of oxidation of hippuric acid
with phosphato-Bi(V) complex have been investigated in phosphoric acid –HClO4
mixture. The reaction is first order in [oxidant] and fractional
order — each in [hippuric acid] and [H+].
Ionic strength has inverse effect on the reaction rate. The effect of added
[Bi(III)] is found to be negligible. An outer sphere mechanism consistent with
the observed kinetics has been proposed and rate law is derived as|
|Appears in Collections:||IJC-A Vol.42A(07) [July 2003]|
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