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|Title:||Kinetics of oxidation of iodide ion by trans-(cyclohexane-l ,2-diamine N,N,N',N' tetraacetato)manganate(III) weakly acidic solution|
|Abstract:||Kinetics of redox reaction between Iˉ and [MnIII(cdta)]ˉ has been investigated in aqueous solution by a stopped-flow technique at pH 3.26 (acetate buffer) and at 30, 35 40 and 45°C. The overall reaction is third order-first order in [MnIII(cdta)ˉ] and second order in [Iˉ]. Though no direct evidence has been obtained, an inner-sphere mechanism has been proposed based on the lability of the complex and is supported by the large negative value of ΔS# (-168 ± 6) JK-1 mol-1.|
|Appears in Collections:||IJC-A Vol.42A(03) [March 2003]|
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