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Title: Solvent-solute interactions in the reaction between p-NOrbenzyl bromide and thiourea-A kinetic study
Authors: Kalyani, P
Manikyamba, P
Issue Date: Jan-2003
Publisher: NISCAIR-CSIR, India
Abstract: The reaction between p-NO2 benzyl bromide and thiourea has been studied in different protic and dipolar aprotic solvents. The reaction is overall second order.Correlation of rate data with different solvent parameters indicates that, the reaction rate is simultaneously influenced by polarity and hydrogen bond donor and acceptor abilities of the solvent. From the linears multiple regression analysis, information regarding the relative solvation of the reactants and the transition state is obtained and the salvation model is proposed.
Page(s): 75-78
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.42A(01) [January 2003]

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