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Title: Evaluation of excess thermodynamic properties in some binary mixtures of o-chlorophenol
Authors: Rao, G V Rama
Sarma, A Viswanatha
Rambabu, C
Issue Date: Dec-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl.7 G01N
Abstract: Ultrasonic velocity, density and viscosity measurements in binary mixtures of o-chlorophenol (1)+ethyl benzoate (2)+anisic aldehyde (2)+acetonitrile (2) are reported at 303.15, 308.15, 313.15, and 318.15K over the entire range of composition. From the experimental data, other related thermodynamic parameters viz, adiabatic compressibility, intermolecular free length, molar volume, excess adiabatic compressibility, excess viscosity, excess molar volume, Rao's constant and Wada's constant have been calculated. The deviation from ideality of these parameters is explained on the basis of molecular interactions between the constituent components of the mixture.
Page(s): 2518-2528
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections: IJC-A Vol.43A(12) [December 2004]

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