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Title: Silyl nitrogen compound: Part XV — Reactions of nonmetal halides with silylated tosylhydrazines
Authors: Vasisht, S K
Sharma, Anuradha
Issue Date: Oct-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl. 7 C0F 7/10
Abstract: Nonmetal halides EXn (E = C, Si, P, As, S; X = Br, Cl) and halogens (X= Br2,I2) react with bis(trimethylsilyl)tosylhydrazine, (Me3Si)2 TsN2H to form tosylhydrazides, EXn-1 (Me3Si)TsN2H, which on heating in vacuum, form a variety of azanes, hydrozones, diazenes and phophazanes. Ditosyltetrazene intermediate formed by dimerisation decomposes into ditosylhydrazine wi th liberation of nitrogen gas.
Page(s): 2113-2119
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(10) [October 2004]

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