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|Title:||Silyl nitrogen compound: Part XV — Reactions of nonmetal halides with silylated tosylhydrazines|
|Authors:||Vasisht, S K|
|IPC Code:||Int. Cl. 7 C0F 7/10|
|Abstract:||Nonmetal halides EXn (E = C, Si, P, As, S; X = Br, Cl) and halogens (X= Br2,I2) react with bis(trimethylsilyl)tosylhydrazine, (Me3Si)2 TsN2H to form tosylhydrazides, EXn-1 (Me3Si)TsN2H, which on heating in vacuum, form a variety of azanes, hydrozones, diazenes and phophazanes. Ditosyltetrazene intermediate formed by dimerisation decomposes into ditosylhydrazine wi th liberation of nitrogen gas.|
|Appears in Collections:||IJC-A Vol.43A(10) [October 2004]|
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